Biomembranes Part O: Protons and Water: Structure and by Lester Packer (Eds.)

By Lester Packer (Eds.)

The seriously acclaimed laboratory commonplace, Methods in Enzymology, is without doubt one of the so much hugely revered guides within the box of biochemistry. seeing that 1955, each one quantity has been eagerly awaited, often consulted, and praised through researchers and reviewers alike. The sequence comprises a lot fabric nonetheless correct this present day - really a necessary e-book for researchers in all fields of existence sciences

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Extra info for Biomembranes Part O: Protons and Water: Structure and Translocation

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Ser. (133), p. 547 (1980). 5t R. W. " Dover, New York, 1962. 206 ,z F r o m C. V. K r i s h n a n and H. L. Friedman, J. Solution Chem. 3, 727 (1974), Fig. 3, with permission. All details, s u c h as the basis for the single-ion values s h o w n here, are given in this paper. the pair interaction in the solvent, and a volume factor which depends on the sizes of a and b and the distance between them. Such models have been applied to a variety of aqueous solutions. 43'45'48'5°'5zFor example, the data in the table were obtained by fitting the model potentials to the data for the solubility of normal alkanes in solutions of tetra(alkyl)ammonium bromides.

London Ser. A 390, 353 (1983). 16 [1] WATER, IONS, AND BIOMOLECULES gNiNi(r) t l I 0 I 2 i I 4 ~ I 6 B I 8 I r/~ FIG. 7. 35 m NiC12 in water. From G. W. Neilson and J. E. Enderby, Proc. R. Soc. London Ser. A 390, 353 (1983) with permission. 9 A, the diameter of the spherical envelope around the hydration complex Ni(H20)~ +, which is relevant because in this state of the solution the nickel ions are found in hexaaquo complexes, as already noted in the discussion of Fig. 6. While a picture of the close-approach configuration that is consistent with the integrity of the colliding hexaaquo complexes can be found, 43 this phenomenon invites the application of the canonical method of structure determination to get a definitive picture.

K. Mehrotra, F. T. Marchese, V. Thirumalai, and G. RaviShanker, Ann. N . Y . Acad. Sci. 367, 108 (1981). 34 WATER, IONS, AND BIOMOLECULES [2] J 1 , , I"'".. )'-" :,...... , \ FIG. 3. Primary solvation regions of the formaldehyde molecule. an N-particle configuration of the system R N, R N = { R t , R2 . . . RN} (21) Let us collect as a set the solute atoms listed in order of k. The members of this set are the "proximity indices" for solvent molecule i, S(k) (RN). Consider this set as the generalized property of the system in context of GMDF theory: Si(I~N) = {S(iI°) (RN), Sl 2°) (R N) .

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